646636

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646636 (Aldrich)

646636

Aldrich

(S)-(+)-COP-Cl Catalyst


CAS Number:	612065-01-7
Linear Formula:	C₇₈H₆₆Cl₂Co₂N₂O₂Pd₂
Molecular Weight:	1464.98
MDL number:	MFCD06798109
PubChem Substance ID:	24883474

Specifications

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Description

Application	Ligand employed in the palladium-catalyzed rearrangement of allylic trichloracetimidates to allylic amines of high enantiopurity.¹
Packaging	1 g in glass btl
	250 mg in glass btl

Properties

optical activity	[α]20/D +1201°, c = 0.1 in methylene chloride
mp	204-205 °C(lit.)

Safety

Personal Protective Equipment	Eyeshields, Gloves, Respirators
Safety Statements	22-24/25
WGK Germany	3

References

Cited Reference

1. J. Am. Chem. Soc. 125, 12412, (2003) Abstract

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